Spectral Signatures of Oxidation States in a Manganese‐Oxo Cubane Water Oxidation Catalyst

We report IR and UV/Vis spectroscopic signatures that allow discriminating between the oxidation states of the manganese‐based water oxidation catalyst [(Mn(4)O(4))(V(4)O(13))(OAc)(3)](3−). Simulated IR spectra show that V=O stretching vibrations in the 900–1000 cm(−1) region shift consistently by a...

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Detalles Bibliográficos
Autores principales: Mai, Sebastian, Klingler, Sarah, Trentin, Ivan, Kund, Julian, Holzer, Marcus, Andreeva, Anastasia, Stach, Robert, Kranz, Christine, Streb, Carsten, Mizaikoff, Boris, González, Leticia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9293465/
https://www.ncbi.nlm.nih.gov/pubmed/34523763
http://dx.doi.org/10.1002/chem.202102583

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9293465/
https://www.ncbi.nlm.nih.gov/pubmed/34523763
http://dx.doi.org/10.1002/chem.202102583

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