Stabilization of Glucosyl Dioxolenium Ions by “Dual Participation” of the 2,2-Dimethyl-2-(ortho-nitrophenyl)acetyl (DMNPA) Protection Group for 1,2-cis-Glucosylation

[Image: see text] The stereoselective introduction of glycosidic bonds is of paramount importance to oligosaccharide synthesis. Among the various chemical strategies to steer stereoselectivity, participation by either neighboring or distal acyl groups is used particularly often. Recently, the use of...

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Detalles Bibliográficos
Autores principales: Remmerswaal, Wouter A., Houthuijs, Kas J., van de Ven, Roel, Elferink, Hidde, Hansen, Thomas, Berden, Giel, Overkleeft, Herman S., van der Marel, Gijsbert A., Rutjes, Floris P. J. T., Filippov, Dmitri V., Boltje, Thomas J., Martens, Jonathan, Oomens, Jos, Codée, Jeroen D. C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9295149/
https://www.ncbi.nlm.nih.gov/pubmed/35748115
http://dx.doi.org/10.1021/acs.joc.2c00808

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9295149/
https://www.ncbi.nlm.nih.gov/pubmed/35748115
http://dx.doi.org/10.1021/acs.joc.2c00808

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