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Engendering reactivity at group 5-heteroatom multiple bonds via π-loading

In this Perspective, we discuss the strategy of π-loading, i.e., coordination of two or more strongly π-donating ligands to a single metal center, as it applies to promoting reactivity at group 5 transition metal-imido groups. When multiple π-donor ligands compete to interact with the same symmetric...

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Detalles Bibliográficos
Autores principales: Fostvedt, Jade I., Mendoza, Jocelyne, Lopez-Flores, Sacy, Alcantar, Diego, Bergman, Robert G., Arnold, John
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9297388/
https://www.ncbi.nlm.nih.gov/pubmed/35919706
http://dx.doi.org/10.1039/d2sc02706b