NHC induced radical formation via homolytic cleavage of B–B bonds and its role in organic reactions

New borylation methodologies have been reported recently, wherein diboron(4) compounds apparently participate in free radical couplings via the homolytic cleavage of the B–B bond. We report herein that bis-NHC adducts of the type (NHC)(2)·B(2)(OR)(4), which are thermally unstable and undergo intramo...

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Detalles Bibliográficos
Autores principales: Kuehn, Laura, Zapf, Ludwig, Werner, Luis, Stang, Martin, Würtemberger-Pietsch, Sabrina, Krummenacher, Ivo, Braunschweig, Holger, Lacôte, Emmanuel, Marder, Todd B., Radius, Udo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9297536/
https://www.ncbi.nlm.nih.gov/pubmed/35919710
http://dx.doi.org/10.1039/d2sc02096c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9297536/
https://www.ncbi.nlm.nih.gov/pubmed/35919710
http://dx.doi.org/10.1039/d2sc02096c

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