Cu(ii)/SPDO complex catalyzed asymmetric Baeyer–Villiger oxidation of 2-arylcyclobutanones and its application for the total synthesis of eupomatilones 5 and 6

A novel classical kinetic resolution of 2-aryl-substituted or 2,3-disubstituted cyclobutanones of Baeyer–Villiger oxidation catalyzed by a Cu(ii)/SPDO complex is reported for the first time, producing normal lactones in excellent enantioselectivities (up to 96% ee) and regioselectivities (up to >...

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Detalles Bibliográficos
Autores principales: Zhang, Chang-Sheng, Shao, Ya-Ping, Zhang, Fu-Min, Han, Xue, Zhang, Xiao-Ming, Zhang, Kun, Tu, Yong-Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9297696/
https://www.ncbi.nlm.nih.gov/pubmed/35919715
http://dx.doi.org/10.1039/d2sc02079c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9297696/
https://www.ncbi.nlm.nih.gov/pubmed/35919715
http://dx.doi.org/10.1039/d2sc02079c

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