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Cyano(triphenylsilyl)phosphanide as a Building Block for P,C,N Conjugated Molecules

The cyano(triphenylsilyl)phosphanide anion was prepared as a sodium salt from 2‐phosphaethynolate. The electronic structure of this new cyano(silyl)phosphanide was studied via computational methods and its reactivity investigated using various electrophiles and Lewis acids, demonstrating its P‐ and...

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Detalles Bibliográficos
Autores principales: Le Corre, Grégoire, Gamboa‐Carballo, Juan José, Li, Zhongshu, Grützmacher, Hansjörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9297940/
https://www.ncbi.nlm.nih.gov/pubmed/34463413
http://dx.doi.org/10.1002/anie.202108295