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Reactivity of the Bicyclic Amido‐Substituted Silicon(I) Ring Compound Si(4){N(SiMe(3))Mes}(4) with FLP‐Type Character

The bicyclic amido‐substituted silicon(I) ring compound Si(4){N(SiMe(3))Mes}(4) 2 (Mes=Mesityl=2,4,6‐Me(3)C(6)H(2)) features enhanced zwitterionic character and different reactivity from the analogous compound Si(4){N(SiMe(3))Dipp}(4) 1 (Dipp=2,6‐( i )Pr(2)C(6)H(3)) due to the smaller mesityl substi...

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Detalles Bibliográficos
Autores principales: Schwedtmann, Kevin, Quest, Michael, Guddorf, Benedikt J., Keuter, Jan, Hepp, Alexander, Feldt, Milica, Droste, Jörn, Hansen, Michael Ryan, Lips, Felicitas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9297995/
https://www.ncbi.nlm.nih.gov/pubmed/34636454
http://dx.doi.org/10.1002/chem.202103101