Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO(2) in the Presence of Silylhalides

The frustrated Lewis pair (FLP) derived from 2,6‐lutidine and B(C(6)F(5))(3) is shown to mediate the catalytic hydrogenation of CO(2) using H(2) as the reductant and a silylhalide as an oxophile. The nature of the products can be controlled with the judicious selection of the silylhalide and the sol...

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Detalles Bibliográficos
Autores principales: Wang, Tongtong, Xu, Maotong, Jupp, Andrew R., Qu, Zheng‐Wang, Grimme, Stefan, Stephan, Douglas W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298004/
https://www.ncbi.nlm.nih.gov/pubmed/34606160
http://dx.doi.org/10.1002/anie.202112233

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298004/
https://www.ncbi.nlm.nih.gov/pubmed/34606160
http://dx.doi.org/10.1002/anie.202112233

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