Rapid Iron(III)−Fluoride‐Mediated Hydrogen Atom Transfer

We anticipate high‐valent metal–fluoride species will be highly effective hydrogen atom transfer (HAT) oxidants because of the magnitude of the H−F bond (in the product) that drives HAT oxidation. We prepared a dimeric Fe(III)(F)−F−Fe(III)(F) complex (1) by reacting [Fe(II)(NCCH(3))(2)(TPA)](ClO(4))...

Descripción completa

Detalles Bibliográficos
Autores principales: Panda, Chakadola, Doyle, Lorna M., Gericke, Robert, McDonald, Aidan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298026/
https://www.ncbi.nlm.nih.gov/pubmed/34582619
http://dx.doi.org/10.1002/anie.202112683

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298026/
https://www.ncbi.nlm.nih.gov/pubmed/34582619
http://dx.doi.org/10.1002/anie.202112683

Ejemplares similares