Gold‐Catalyzed Reaction of Propargyl Esters and Alkynylsilanes: Synthesis of Vinylallene Derivatives through a Twofold 1,2‐Rearrangement

The reaction of propargyl esters with alkynylsilanes under gold catalysis provides vinylallene derivatives through consecutive [1,2]‐acyloxy/[1,2]‐silyl rearrangements. Good yields, full atom‐economy, broad substrate scope, easy scale‐up and low catalyst loadings are salient features of this novel t...

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Detalles Bibliográficos
Autores principales: Bernardo, Olaya, González‐Pelayo, Silvia, Fernández, Israel, López, Luis A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298039/
https://www.ncbi.nlm.nih.gov/pubmed/34581473
http://dx.doi.org/10.1002/anie.202110783

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298039/
https://www.ncbi.nlm.nih.gov/pubmed/34581473
http://dx.doi.org/10.1002/anie.202110783

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