Metal Centers as Nucleophiles: Oxymoron of Halogen Bond‐Involving Crystal Engineering

This review highlights recent studies discovering unconventional halogen bonding (HaB) that involves positively charged metal centers. These centers provide their filled d‐orbitals for HaB, and thus behave as nucleophilic components toward the noncovalent interaction. This role of some electron‐rich...

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Detalles Bibliográficos
Autores principales: Ivanov, Daniil M., Bokach, Nadezhda A., Yu. Kukushkin, Vadim, Frontera, Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Minireviews
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298210/
https://www.ncbi.nlm.nih.gov/pubmed/34623005
http://dx.doi.org/10.1002/chem.202103173

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298210/
https://www.ncbi.nlm.nih.gov/pubmed/34623005
http://dx.doi.org/10.1002/chem.202103173

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