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Fluorination Reactions at a Platinum Carbene Complex: Reaction Routes to SF(3), S(=O)F and Fluorido Complexes
The electron‐rich Pt complex [Pt(IMes)(2)] (IMes: [1,3‐bis(2,4,6‐trimethylphenyl)‐2‐imidazolinylidine]) can be used as precursor for the syntheses of a variety of fluorido ligand containing compounds. The sulfur fluoride SF(4) undergoes a rapid oxidative addition at Pt(0) to yield trans‐[Pt(F)(SF(3)...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298267/ https://www.ncbi.nlm.nih.gov/pubmed/34634177 http://dx.doi.org/10.1002/chem.202103311 |