Inherent Reactivity of Spiro‐Activated Electrophilic Cyclopropanes

The kinetics of the ring‐opening reactions of thiophenolates with geminal bis(acceptor)‐substituted cyclopropanes in DMSO at 20 °C was monitored by photometric methods. The determined second‐order rate constants of the S(N)2 reactions followed linear relationships with Mayr nucleophilicity parameter...

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Detalles Bibliográficos
Autores principales: Jüstel, Patrick M., Stan, Alexandra, Pignot, Cedric D., Ofial, Armin R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298281/
https://www.ncbi.nlm.nih.gov/pubmed/34569669
http://dx.doi.org/10.1002/chem.202103027

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298281/
https://www.ncbi.nlm.nih.gov/pubmed/34569669
http://dx.doi.org/10.1002/chem.202103027

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