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Spin‐Phonon Coupling and Slow‐Magnetic Relaxation in Pristine Ferrocenium

We report the spin dynamic properties of non‐substituted ferrocenium complexes. Ferrocenium shows a field‐induced single‐molecule magnet behaviour in DMF solution while cobaltocene lacks slow spin relaxation neither in powder nor in solution. Multireference quantum mechanical calculations give a non...

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Detalles Bibliográficos
Autores principales: Amoza, Martín, Maxwell, Lindley, Aliaga‐Alcalde, Núria, Gómez‐Coca, Silvia, Ruiz, Eliseo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298439/
https://www.ncbi.nlm.nih.gov/pubmed/34582589
http://dx.doi.org/10.1002/chem.202102603