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Spin‐Phonon Coupling and Slow‐Magnetic Relaxation in Pristine Ferrocenium
We report the spin dynamic properties of non‐substituted ferrocenium complexes. Ferrocenium shows a field‐induced single‐molecule magnet behaviour in DMF solution while cobaltocene lacks slow spin relaxation neither in powder nor in solution. Multireference quantum mechanical calculations give a non...
Autores principales: | Amoza, Martín, Maxwell, Lindley, Aliaga‐Alcalde, Núria, Gómez‐Coca, Silvia, Ruiz, Eliseo |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298439/ https://www.ncbi.nlm.nih.gov/pubmed/34582589 http://dx.doi.org/10.1002/chem.202102603 |
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