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Conversion of E(4) (E(4)=P(4), As(4), AsP(3)) by Ni(0) and Ni(I) Synthons – A Comparative Study

The reactivity of white phosphorus and yellow arsenic towards two different nickel nacnac complexes is investigated. The nickel complexes [(L(1)Ni)(2)tol] (1, L(1)=[{N(C(6)H(3) (i)Pr(2)‐2,6)C(Me)}(2)CH](−)) and [K(2)][(L(1)Ni)(2)(μ,η(1 : 1)‐N(2))] (6) were reacted with P(4), As(4) and the interpnict...

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Detalles Bibliográficos
Autores principales: Haimerl, Maria, Graßl, Christian, Seidl, Michael, Piesch, Martin, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298694/
https://www.ncbi.nlm.nih.gov/pubmed/34730858
http://dx.doi.org/10.1002/chem.202103372