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A Five‐Coordinate Compound with Inverted Ligand Field: An Unprecedented Geometry for Silver(III)
By using suitable synthetic procedures, we have first isolated the square‐planar organosilver(III) compounds [PPh(4)][trans‐(CF(3))(2)AgX(2)] [X=Cl (1 a), Br (2 a)]. The geometry and stereochemistry of the chloro‐derivative 1 a have been unambiguously established by single‐crystal X‐ray diffraction...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298700/ https://www.ncbi.nlm.nih.gov/pubmed/34596935 http://dx.doi.org/10.1002/anie.202112449 |