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Divergent Reactivity of an Isolable Nickelacyclobutane

Nickelacyclobutanes are mostly invoked as reactive intermediates in the reaction of nickel carbenes and olefins to yield cyclopropanes. Nevertheless, early work suggested that other decomposition routes such as β‐hydride elimination and even metathesis could be accessible. Herein, we report the isol...

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Detalles Bibliográficos
Autores principales: Sansores‐Paredes, María L. G., van der Voort, Storm, Lutz, Martin, Moret, Marc‐Etienne
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298726/
https://www.ncbi.nlm.nih.gov/pubmed/34608737
http://dx.doi.org/10.1002/anie.202111389