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A Striking Mode of Activation of Carbon Disulfide with a Cooperative Bis(silylene)
The reactivity of the 1,4‐substituted bis(silylenyl)terphenylene 1, 1,4‐[ortho‐(LSi)C(6)H(4)](2)C(6)H(4), (L=RC(NtBu)(2), R=Ph, Mes) towards CS(2) is reported. It results in a dearomatization of the phenylene ring, affording the 1,3‐substituted cyclohexadiene derivative 2. According to DFT calculati...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298776/ https://www.ncbi.nlm.nih.gov/pubmed/34670015 http://dx.doi.org/10.1002/anie.202110398 |