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A Striking Mode of Activation of Carbon Disulfide with a Cooperative Bis(silylene)

The reactivity of the 1,4‐substituted bis(silylenyl)terphenylene 1, 1,4‐[ortho‐(LSi)C(6)H(4)](2)C(6)H(4), (L=RC(NtBu)(2), R=Ph, Mes) towards CS(2) is reported. It results in a dearomatization of the phenylene ring, affording the 1,3‐substituted cyclohexadiene derivative 2. According to DFT calculati...

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Detalles Bibliográficos
Autores principales:	Luecke, Marcel‐Philip, Giarrana, Luisa, Kostenko, Arseni, Gensch, Tobias, Yao, Shenglai, Driess, Matthias
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298776/ https://www.ncbi.nlm.nih.gov/pubmed/34670015 http://dx.doi.org/10.1002/anie.202110398

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