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A Phosphorus‐Based Pacman Dication Generated by Cooperative Self‐Activation of a Pacman Phosphane
Formal coordination of phosphorus(III) by a calix[4]pyrrole Schiff base ligand was achieved through the reaction of this ligand with PCl(3) under basic conditions. The reaction product adopts a Pacman conformation with two P−Cl moieties, one in exo and one in endo position. It represents the first n...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298836/ https://www.ncbi.nlm.nih.gov/pubmed/34761445 http://dx.doi.org/10.1002/chem.202103983 |