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A Strategy for Site‐ and Chemoselective C−H Alkenylation through Osmaelectrooxidative Catalysis

Herein, we disclose osmaelectrocatalyzed C−H activations that set the stage for electrooxidative alkyne annulations by benzoic acids. The osmium electrocatalysis enables site‐ and chemoselective electrooxidative C−H activations with unique levels of selectivity. The isolation of unprecedented osmium...

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Detalles Bibliográficos
Autores principales: Choi, Isaac, Messinis, Antonis M., Hou, Xiaoyan, Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298884/
https://www.ncbi.nlm.nih.gov/pubmed/34665924
http://dx.doi.org/10.1002/anie.202110616