Critical Assessment of the Reducing Ability of Breslow‐type Derivatives and Implications for Carbene‐Catalyzed Radical Reactions

We report the synthesis of acyl azolium salts stemming from thiazolylidenes C(NS) , triazolylidenes C(TN) (,) mesoionic carbenes C(MIC) and the generation of their corresponding radicals and enolates, covering about 60 Breslow‐type derivatives. This study highlights the role of additives in the redo...

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Detalles Bibliográficos
Autores principales: Delfau, Ludivine, Nichilo, Samantha, Molton, Florian, Broggi, Julie, Tomás‐Mendivil, Eder, Martin, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299025/
https://www.ncbi.nlm.nih.gov/pubmed/34651408
http://dx.doi.org/10.1002/anie.202111988

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299025/
https://www.ncbi.nlm.nih.gov/pubmed/34651408
http://dx.doi.org/10.1002/anie.202111988

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