Stabilization of Reactive Nitrene by Silylenes without Using a Reducing Metal

Herein, we report the stabilization of nitrene reagents as the source of a nitrogen atom to synthesize nitrogen‐incorporated R(1)LSi‐N←SiLR(2) (1) [L=PhC(NtBu)(2); R(1)=NTMS(2), R(2)=NTMS]. Compound 1 is synthesized by reacting LSi(I)‐Si(I)L with 3.1 equivalents of Me(3)SiN(3) at low temperature to...

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Detalles Bibliográficos
Autores principales: Ding, Yi, Sarkar, Samir Kumar, Nazish, Mohd, Muhammed, Shahila, Lüert, Daniel, Ruth, Paul Niklas, Legendre, Christina M., Herbst‐Irmer, Regine, Parameswaran, Pattiyil, Stalke, Dietmar, Yang, Zhi, Roesky, Herbert W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299049/
https://www.ncbi.nlm.nih.gov/pubmed/34545990
http://dx.doi.org/10.1002/anie.202110456

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299049/
https://www.ncbi.nlm.nih.gov/pubmed/34545990
http://dx.doi.org/10.1002/anie.202110456

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