An NHC‐Stabilized H(2)GeBH(2) Precursor for the Preparation of Cationic Group 13/14/15 Hydride Chains

The synthesis, characterization and reactivity studies of the NHC‐stabilized complex IDipp ⋅ GeH(2)BH(2)OTf (1) (IDipp=1,3‐bis(2,6‐diisopropylphenyl)imidazolin‐2‐ylidene) are reported. Nucleophilic substitution of the triflate (OTf) group in 1 by phosphine or arsine donors provides access to the cat...

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Detalles Bibliográficos
Autores principales: Ackermann, Matthias T., Seidl, Michael, Wen, Fuwei, Ferguson, Michael J., Timoshkin, Alexey Y., Rivard, Eric, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299135/
https://www.ncbi.nlm.nih.gov/pubmed/34761837
http://dx.doi.org/10.1002/chem.202103780

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299135/
https://www.ncbi.nlm.nih.gov/pubmed/34761837
http://dx.doi.org/10.1002/chem.202103780

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