Cargando…

An NHC‐Stabilized H(2)GeBH(2) Precursor for the Preparation of Cationic Group 13/14/15 Hydride Chains

The synthesis, characterization and reactivity studies of the NHC‐stabilized complex IDipp ⋅ GeH(2)BH(2)OTf (1) (IDipp=1,3‐bis(2,6‐diisopropylphenyl)imidazolin‐2‐ylidene) are reported. Nucleophilic substitution of the triflate (OTf) group in 1 by phosphine or arsine donors provides access to the cat...

Descripción completa

Detalles Bibliográficos
Autores principales:	Ackermann, Matthias T., Seidl, Michael, Wen, Fuwei, Ferguson, Michael J., Timoshkin, Alexey Y., Rivard, Eric, Scheer, Manfred
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299135/ https://www.ncbi.nlm.nih.gov/pubmed/34761837 http://dx.doi.org/10.1002/chem.202103780

Ejemplares similares

NHC‐stabilized Parent Arsanylalanes and ‐gallanes
por: Weinhart, Michael A. K., et al.
Publicado: (2020)

A convenient route to mixed cationic group 13/14/15 compounds
por: Ackermann, Matthias T., et al.
Publicado: (2023)

Coordination of Pnictogenylboranes Towards Tl(I) Salts and a Tl‐ Mediated P−P Coupling
por: Szlosek, Robert, et al.
Publicado: (2022)

Monomeric β‐Diketiminato Group 13 Metal Dipnictogenide Complexes with Two Terminal EH(2) Groups (E=P, As)
por: Li, Bin, et al.
Publicado: (2019)

NHC-CDI Betaine Adducts and Their Cationic Derivatives as Catalyst Precursors for Dichloromethane Valorization
por: Sánchez-Roa, David, et al.
Publicado: (2021)

A Cationic NHC‐Supported Borole
por: Heitkemper, Tobias, et al.
Publicado: (2020)

NHCs as Neutral Donors towards Polyphosphorus Complexes
por: Riedlberger, Felix, et al.
Publicado: (2020)

(NHC)Pd(II) hydride-catalyzed dehydroaromatization by olefin chain-walking isomerization and transfer-dehydrogenation
por: Chen, Weihao, et al.
Publicado: (2022)

Quantification of the hydride donor abilities of NADH, NADPH, and BH(3)CN(−) in water
por: Mayer, Robert J., et al.
Publicado: (2022)

NHC‐Coordinated Diphosphene‐Stabilized Gold(I) Hydride and Its Reversible Conversion to Gold(I) Formate with CO(2)
por: Dhara, Debabrata, et al.
Publicado: (2019)

Reactivity and Structure of a Bis-phenolate Niobium NHC Complex
por: Neururer, Florian R., et al.
Publicado: (2022)

Anion influences on reactivity and NMR spectroscopic features of NHC precursors
por: Huynh, Han Vinh, et al.
Publicado: (2018)

Heptanuclear Silver Hydride Clusters as Catalytic Precursors for the Reduction of 4-Nitrophenol
por: Yusuf, Tunde L., et al.
Publicado: (2022)

Reductive α-borylation of α,β-unsaturated esters using NHC–BH(3) activated by I(2) as a metal-free route to α-boryl esters
por: Radcliffe, James E., et al.
Publicado: (2018)

Redox and Coordination Behavior of the Hexaphosphabenzene Ligand in [(Cp*Mo)(2)(μ,η(6):η(6)-P(6))] Towards the “Naked” Cations Cu(+), Ag(+), and Tl(+)
por: Fleischmann, Martin, et al.
Publicado: (2015)

Molecular Zinc Hydride Cations [ZnH](+): Synthesis, Structure, and CO(2) Hydrosilylation Catalysis
por: Ritter, Florian, et al.
Publicado: (2020)

An NHC‐Mediated Metal‐Free Approach towards an NHC‐Coordinated Endocyclic Disilene
por: Lainer, Thomas, et al.
Publicado: (2022)

The Effect of Hydrogen and Hydrides on the Integrity of Zirconium Alloy Components: Delayed Hydride Cracking
por: Puls, Manfred P
Publicado: (2012)

Anion- or Cation-Exchange Membranes for NaBH(4)/H(2)O(2) Fuel Cells?
por: Šljukić, Biljana, et al.
Publicado: (2012)

Cationic Noble-Gas Hydrides: From Ion Sources to Outer Space
por: Grandinetti, Felice
Publicado: (2020)

Regioselective Hydrosilylation of Olefins Catalyzed by a Molecular Calcium Hydride Cation
por: Schuhknecht, Danny, et al.
Publicado: (2019)

Computational Characterization of Astrophysical Species: The Case of Noble Gas Hydride Cations
por: Montes de Oca-Estévez, María Judit, et al.
Publicado: (2021)

Phosphanylalanes and Phosphanylgallanes Stabilized only by a Lewis Base
por: Weinhart, Michael A. K., et al.
Publicado: (2020)

NHC stabilized copper nanoparticles via reduction of a copper NHC complex
por: Richstein, Robert, et al.
Publicado: (2023)

Preorganized Ag(I) Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers
por: Moussa, Mehdi Elsayed, et al.
Publicado: (2017)

Linking of Cu(I) Units by Tetrahedral Mo(2)E(2) Complexes (E=P, As)
por: Schiller, Jana, et al.
Publicado: (2020)

Synthesis of asymmetric [bis(imidazolyl)-BH(2)](+)-cation-based ionic liquids as potential rocket fuels
por: Li, Xue, et al.
Publicado: (2021)

Halogenation of the Hexaphosphabenzene Complex [(Cp*Mo)(2)(μ,η(6):η(6)‐P(6))]: Snapshots on the Reaction Progress
por: Garbagnati, Anna, et al.
Publicado: (2022)

Cationic Functionalisation by Phosphenium Ion Insertion
por: Riesinger, Christoph, et al.
Publicado: (2020)

Cationic NHC‐Phosphine Iridium Complexes: Highly Active Catalysts for Base‐Free Hydrogenation of Ketones
por: Quan, Xu, et al.
Publicado: (2020)

The Potential of the Diphosphorus Complex [Cp(2)W(2)(CO)(4)(η(2)‐P(2))] as an Organometallic Connecter in Supramolecular Chemistry
por: Elsayed Moussa, Mehdi, et al.
Publicado: (2019)

Diantimony Complexes [Cp(R) (2)Mo(2)(CO)(4)(μ,η(2)‐Sb(2))] (Cp(R)=C(5)H(5), C(5)H(4) (t)Bu) as Unexpected Ligands Stabilizing Silver(I)( n ) (n=1–4) Monomers, Dimers and Chains
por: Shelyganov, Pavel A., et al.
Publicado: (2023)

Metal-Free Addition/Head-to-Tail Polymerization of Transient Phosphinoboranes, RPH-BH(2): A Route to Poly(alkylphosphinoboranes)
por: Marquardt, Christian, et al.
Publicado: (2015)

Structural diversity of mixed polypnictogen complexes: dicationic E(2)E′(2) (E ≠ E′ = P, As, Sb, Bi) chains, cycles and cages stabilized by transition metals
por: Dütsch, Luis, et al.
Publicado: (2021)

Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex
por: Zhan, Licheng, et al.
Publicado: (2020)

Dinuclear gold(I) Complexes with Bidentate NHC Ligands as Precursors for Alkynyl Complexes via Mechanochemistry
por: Stoppa, Valentina, et al.
Publicado: (2022)

The Cobalt cyclo‐P(4) Sandwich Complex and Its Role in the Formation of Polyphosphorus Compounds
por: Dielmann, Fabian, et al.
Publicado: (2017)

Electrochemical C–H bond activation via cationic iridium hydride pincer complexes
por: Lindley, Brian M., et al.
Publicado: (2019)

Alkali Metal Cation Affinities of Neutral Maingroup-Element Hydrides across the Periodic Table
por: Boughlala, Zakaria, et al.
Publicado: (2019)

Technical specification of new coils for the bending magnets BH2 and BH5
Publicado: (1981)

Cannot write session to /tmp/vufind_sessions/sess_8gnbmhclpmg4m1jp91blp0t8ph