Probing the Boundaries between Lewis‐Basic and Redox Behavior of a Parent Borylene

The parent borylene (CAAC)(Me(3)P)BH, 1 (CAAC=cyclic alkyl(amino)carbene), acts both as a Lewis base and one‐electron reducing agent towards group 13 trichlorides (ECl(3), E=B, Al, Ga, In), yielding the adducts 1‐ECl(3) and increasing proportions of the radical cation [1](•+) for the heavier group 1...

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Detalles Bibliográficos
Autores principales: Arrowsmith, Merle, Endres, Sara, Heinz, Myron, Nestler, Vincent, Holthausen, Max C., Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299150/
https://www.ncbi.nlm.nih.gov/pubmed/34596278
http://dx.doi.org/10.1002/chem.202103256

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299150/
https://www.ncbi.nlm.nih.gov/pubmed/34596278
http://dx.doi.org/10.1002/chem.202103256

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