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Probing the Boundaries between Lewis‐Basic and Redox Behavior of a Parent Borylene
The parent borylene (CAAC)(Me(3)P)BH, 1 (CAAC=cyclic alkyl(amino)carbene), acts both as a Lewis base and one‐electron reducing agent towards group 13 trichlorides (ECl(3), E=B, Al, Ga, In), yielding the adducts 1‐ECl(3) and increasing proportions of the radical cation [1](•+) for the heavier group 1...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299150/ https://www.ncbi.nlm.nih.gov/pubmed/34596278 http://dx.doi.org/10.1002/chem.202103256 |