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Strong Ligand Stabilization Based on π‐Extension in a Series of Ruthenium Terpyridine Water Oxidation Catalysts

The substitution behavior of the monodentate Cl ligand of a series of ruthenium(II) terpyridine complexes (terpyridine (tpy)=2,2′:6′,2′′‐terpyridine) has been investigated. (1)H NMR kinetic experiments of the dissociation of the chloro ligand in D(2)O for the complexes [Ru(tpy)(bpy)Cl]Cl (1, bpy=2,2...

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Detalles Bibliográficos
Autores principales: Amthor, Sebastian, Hernández‐Castillo, David, Maryasin, Boris, Seeber, Phillip, Mengele, Alexander K., Gräfe, Stefanie, González, Leticia, Rau, Sven
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299156/
https://www.ncbi.nlm.nih.gov/pubmed/34705303
http://dx.doi.org/10.1002/chem.202102905