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Case Study of N‐( i )Pr versus N‐Mes Substituted NHC Ligands in Nickel Chemistry: The Coordination and Cyclotrimerization of Alkynes at [Ni(NHC)(2)]

A case study on the effect of the employment of two different NHC ligands in complexes [Ni(NHC)(2)] (NHC=( i )Pr(2)Im(Me) 1(Me) , Mes(2)Im 2) and their behavior towards alkynes is reported. The reaction of a mixture of [Ni(2)(( i )Pr(2)Im(Me))(4)(μ‐(η ( 2 ) : η(2))‐COD)] B/ [Ni(( i )Pr(2)Im(Me))(2)(...

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Detalles Bibliográficos
Autores principales: Tendera, Lukas, Helm, Moritz, Krahfuss, Mirjam J., Kuntze‐Fechner, Maximilian W., Radius, Udo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299202/
https://www.ncbi.nlm.nih.gov/pubmed/34713939
http://dx.doi.org/10.1002/chem.202103093