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Case Study of N‐( i )Pr versus N‐Mes Substituted NHC Ligands in Nickel Chemistry: The Coordination and Cyclotrimerization of Alkynes at [Ni(NHC)(2)]
A case study on the effect of the employment of two different NHC ligands in complexes [Ni(NHC)(2)] (NHC=( i )Pr(2)Im(Me) 1(Me) , Mes(2)Im 2) and their behavior towards alkynes is reported. The reaction of a mixture of [Ni(2)(( i )Pr(2)Im(Me))(4)(μ‐(η ( 2 ) : η(2))‐COD)] B/ [Ni(( i )Pr(2)Im(Me))(2)(...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299202/ https://www.ncbi.nlm.nih.gov/pubmed/34713939 http://dx.doi.org/10.1002/chem.202103093 |