Tuning Ruthenium Carbene Complexes for Selective P−H Activation through Metal‐Ligand Cooperation

The use of iminophosphoryl‐tethered ruthenium carbene complexes to activate secondary phosphine P−H bonds is reported. Complexes of type [(p‐cymene)‐RuC(SO(2)Ph)(PPh(2)NR)] (with R = SiMe(3) or 4‐C(6)H(4)−NO(2)) were found to exhibit different reactivities depending on the electronics of the applied...

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Detalles Bibliográficos
Autores principales: Feichtner, Kai‐Stephan, Scharf, Lennart T., Scherpf, Thorsten, Mallick, Bert, Boysen, Nils, Gessner, Viktoria H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299219/
https://www.ncbi.nlm.nih.gov/pubmed/34705314
http://dx.doi.org/10.1002/chem.202103151

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299219/
https://www.ncbi.nlm.nih.gov/pubmed/34705314
http://dx.doi.org/10.1002/chem.202103151

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