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Tuning Ruthenium Carbene Complexes for Selective P−H Activation through Metal‐Ligand Cooperation
The use of iminophosphoryl‐tethered ruthenium carbene complexes to activate secondary phosphine P−H bonds is reported. Complexes of type [(p‐cymene)‐RuC(SO(2)Ph)(PPh(2)NR)] (with R = SiMe(3) or 4‐C(6)H(4)−NO(2)) were found to exhibit different reactivities depending on the electronics of the applied...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299219/ https://www.ncbi.nlm.nih.gov/pubmed/34705314 http://dx.doi.org/10.1002/chem.202103151 |