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Rhodium Indenyl NHC and Fluorenyl‐Tethered NHC Half‐Sandwich Complexes: Synthesis, Structures and Applications in the Catalytic C−H Borylation of Arenes and Alkanes

Indenyl (Ind) rhodium N‐heterocyclic carbene (NHC) complexes [Rh(η (5)‐Ind)(NHC)(L)] were synthesised for 1,3‐bis(2,6‐diisopropylphenyl)‐4,5‐dihydroimidazol‐2‐ylidene (SIPr) with L=C(2)H(4) (1), CO (2 a) and cyclooctene (COE; 3), for 1,3‐bis(2,4,6‐trimethylphenyl)‐4,5‐dihydroimidazol‐2‐ylidene (SIMe...

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Detalles Bibliográficos
Autores principales: Evans, Kieren J., Morton, Paul A., Luz, Christian, Miller, Callum, Raine, Olivia, Lynam, Jason M., Mansell, Stephen M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299238/
https://www.ncbi.nlm.nih.gov/pubmed/34653269
http://dx.doi.org/10.1002/chem.202102961