Cargando…

Rhodium Indenyl NHC and Fluorenyl‐Tethered NHC Half‐Sandwich Complexes: Synthesis, Structures and Applications in the Catalytic C−H Borylation of Arenes and Alkanes

Indenyl (Ind) rhodium N‐heterocyclic carbene (NHC) complexes [Rh(η (5)‐Ind)(NHC)(L)] were synthesised for 1,3‐bis(2,6‐diisopropylphenyl)‐4,5‐dihydroimidazol‐2‐ylidene (SIPr) with L=C(2)H(4) (1), CO (2 a) and cyclooctene (COE; 3), for 1,3‐bis(2,4,6‐trimethylphenyl)‐4,5‐dihydroimidazol‐2‐ylidene (SIMe...

Descripción completa

Detalles Bibliográficos
Autores principales:	Evans, Kieren J., Morton, Paul A., Luz, Christian, Miller, Callum, Raine, Olivia, Lynam, Jason M., Mansell, Stephen M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299238/ https://www.ncbi.nlm.nih.gov/pubmed/34653269 http://dx.doi.org/10.1002/chem.202102961

Ejemplares similares

Synergic Deprotonation Generates Alkali‐Metal Salts of Tethered Fluorenide‐NHC Ligands Co‐Complexed to Alkali‐Metal Amides
por: Evans, Kieren J., et al.
Publicado: (2019)

Photoinduced successive oxidative ring-opening and borylation of indolizines with NHC–boranes
por: Zheng, Huitao, et al.
Publicado: (2021)

Synthesis of Imidazolium Cations Linked to Para-t-Butylcalix[4]arene Frameworks and Their Use as Synthons for Nickel-NHC Complexes Tethered to Calix[4]arenes
por: Chetcuti, Michael J., et al.
Publicado: (2023)

Versatile deprotonated NHC: C,N-bridged dinuclear iridium and rhodium complexes
por: Poater, Albert
Publicado: (2016)

Application of Bulky NHC–Rhodium Complexes in Efficient S–Si and S–S Bond Forming Reactions
por: Bołt, Małgorzata, et al.
Publicado: (2021)

Rhodium‐NHC‐Catalyzed gem‐Specific O‐Selective Hydropyridonation of Terminal Alkynes
por: Galiana‐Cameo, María, et al.
Publicado: (2022)

Completing the series of boron-nucleophilic cyanoborates: boryl anions of type NHC–B(CN)(2) (–)
por: Böser, Richard, et al.
Publicado: (2017)

An NHC‐Mediated Metal‐Free Approach towards an NHC‐Coordinated Endocyclic Disilene
por: Lainer, Thomas, et al.
Publicado: (2022)

NHC stabilized copper nanoparticles via reduction of a copper NHC complex
por: Richstein, Robert, et al.
Publicado: (2023)

To “Rollover” or Not? Stereoelectronically Guided C–H Functionalization Pathways from Rhodium–Abnormal NHC Intermediates
por: Dutta, Champak, et al.
Publicado: (2018)

Cooperative NHC/Photoredox Catalyzed Ring‐Opening of Aryl Cyclopropanes to 1‐Aroyloxylated‐3‐Acylated Alkanes
por: Zuo, Zhijun, et al.
Publicado: (2021)

Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles
por: Andrew, Rhiann E., et al.
Publicado: (2016)

Modulating NHC catalysis with fluorine
por: Rey, Yannick P, et al.
Publicado: (2013)

The key role of R–NHC coupling (R = C, H, heteroatom) and M–NHC bond cleavage in the evolution of M/NHC complexes and formation of catalytically active species
por: Chernyshev, Victor M., et al.
Publicado: (2020)

The boron–boron triple bond in NHC→B[triple bond, length as m-dash]B←NHC
por: Holzmann, Nicole, et al.
Publicado: (2015)

Possible Synthetic Approaches for Heterobimetallic Complexes by Using nNHC/tzNHC Heteroditopic Carbene Ligands
por: Longhi, Andrea, et al.
Publicado: (2019)

Moving from Classical Ru-NHC to Neutral or Charged Rh-NHC Based Catalysts in Olefin Metathesis
por: Poater, Albert
Publicado: (2016)

Reductive α-borylation of α,β-unsaturated esters using NHC–BH(3) activated by I(2) as a metal-free route to α-boryl esters
por: Radcliffe, James E., et al.
Publicado: (2018)

A Cationic NHC‐Supported Borole
por: Heitkemper, Tobias, et al.
Publicado: (2020)

NHC-Metallosurfactants as Active Polymerization Catalysts
por: Donner, Adrian, et al.
Publicado: (2019)

NHC‐stabilized Parent Arsanylalanes and ‐gallanes
por: Weinhart, Michael A. K., et al.
Publicado: (2020)

Tri(boryl)alkanes and Tri(boryl)alkenes: The Versatile Reagents
por: Salvadó, Oriol, et al.
Publicado: (2020)

Revealing the unusual role of bases in activation/deactivation of catalytic systems: O–NHC coupling in M/NHC catalysis
por: Chernyshev, Victor M., et al.
Publicado: (2018)

Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen
por: Gyton, Matthew R., et al.
Publicado: (2018)

The divergent effects of strong NHC donation in catalysis
por: Lummiss, Justin A. M., et al.
Publicado: (2015)

Metathesis Reactions of a NHC‐Stabilized Phosphaborene
por: Koner, Abhishek, et al.
Publicado: (2022)

Biological Activities of Ruthenium NHC Complexes: An Update
por: Catalano, Alessia, et al.
Publicado: (2023)

Ag–NHC Complexes in the π-Activation of Alkynes
por: Yang, Shiyi, et al.
Publicado: (2023)

A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes
por: Santoro, Orlando, et al.
Publicado: (2013)

N-Alkylation and N-Methylation of Amines with Alcohols Catalyzed by Nitrile-Substituted NHC–Ir(III) and NHC–Ru(II) Complexes
por: Çakır, Sinem, et al.
Publicado: (2023)

Transamidation of Amides and Amidation of Esters by Selective N–C(O)/O–C(O) Cleavage Mediated by Air- and Moisture-Stable Half-Sandwich Nickel(II)–NHC Complexes
por: Buchspies, Jonathan, et al.
Publicado: (2021)

Stereo- and Chemodivergent NHC-Promoted Functionalisation of Arylalkylketenes with Chloral**
por: Douglas, James J, et al.
Publicado: (2015)

NHC Backbone Configuration in Ruthenium-Catalyzed Olefin Metathesis
por: Paradiso, Veronica, et al.
Publicado: (2016)

NHC-catalyzed covalent activation of heteroatoms for enantioselective reactions
por: Song, Runjiang, et al.
Publicado: (2021)

Structural and Luminescent Properties of Homoleptic Silver(I), Gold(I), and Palladium(II) Complexes with nNHC-tzNHC Heteroditopic Carbene Ligands
por: Monticelli, Marco, et al.
Publicado: (2019)

Coligand role in the NHC nickel catalyzed C–F bond activation: investigations on the insertion of bis(NHC) nickel into the C–F bond of hexafluorobenzene
por: Kuntze-Fechner, Maximilian W., et al.
Publicado: (2020)

Bi- and trinuclear copper(I) complexes of 1,2,3-triazole-tethered NHC ligands: synthesis, structure, and catalytic properties
por: Gu, Shaojin, et al.
Publicado: (2016)

Case Study of N‐( i )Pr versus N‐Mes Substituted NHC Ligands in Nickel Chemistry: The Coordination and Cyclotrimerization of Alkynes at [Ni(NHC)(2)]
por: Tendera, Lukas, et al.
Publicado: (2021)

NHC Polymeric Particles Obtained by Self-Assembly and Click Approach of Calix[4]Arene Amphiphiles as Support for Catalytically Active Pd Nanoclusters
por: Burilov, Vladimir, et al.
Publicado: (2021)

NHC-catalysed highly selective aerobic oxidation of nonactivated aldehydes
por: Möhlmann, Lennart, et al.
Publicado: (2013)

Cannot write session to /tmp/vufind_sessions/sess_l49atobplr9s41e34husdrs0tq