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Leveraging the n→π* Interaction in Alkene Isomerization by Selective Energy Transfer Catalysis
Examples of geometric alkene isomerization in nature are often limited to the net exergonic direction (ΔG°<0), with the antipodal net endergonic processes (ΔG°>0) comparatively under‐represented. Inspired by the expansiveness of the maleate to fumarate (Z→E) isomerization in biochemistry, we i...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299456/ https://www.ncbi.nlm.nih.gov/pubmed/34748684 http://dx.doi.org/10.1002/anie.202113600 |