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Leveraging the n→π* Interaction in Alkene Isomerization by Selective Energy Transfer Catalysis

Examples of geometric alkene isomerization in nature are often limited to the net exergonic direction (ΔG°<0), with the antipodal net endergonic processes (ΔG°>0) comparatively under‐represented. Inspired by the expansiveness of the maleate to fumarate (Z→E) isomerization in biochemistry, we i...

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Detalles Bibliográficos
Autores principales: Neveselý, Tomáš, Molloy, John J., McLaughlin, Calum, Brüss, Linda, Daniliuc, Constantin G., Gilmour, Ryan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299456/
https://www.ncbi.nlm.nih.gov/pubmed/34748684
http://dx.doi.org/10.1002/anie.202113600