Cargando…
Leveraging the n→π* Interaction in Alkene Isomerization by Selective Energy Transfer Catalysis
Examples of geometric alkene isomerization in nature are often limited to the net exergonic direction (ΔG°<0), with the antipodal net endergonic processes (ΔG°>0) comparatively under‐represented. Inspired by the expansiveness of the maleate to fumarate (Z→E) isomerization in biochemistry, we i...
Autores principales: | Neveselý, Tomáš, Molloy, John J., McLaughlin, Calum, Brüss, Linda, Daniliuc, Constantin G., Gilmour, Ryan |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299456/ https://www.ncbi.nlm.nih.gov/pubmed/34748684 http://dx.doi.org/10.1002/anie.202113600 |
Ejemplares similares
-
Regio‐ and Enantioselective Intermolecular Aminofluorination of Alkenes via Iodine(I)/Iodine(III) Catalysis
por: Schäfer, Michael, et al.
Publicado: (2022) -
Illuminating anti-hydrozirconation: controlled geometric isomerization of an organometallic species
por: Hostmann, Theresa, et al.
Publicado: (2021) -
Controllable Isomerization of Alkenes by Dual Visible‐Light‐Cobalt Catalysis
por: Meng, Qing‐Yuan, et al.
Publicado: (2019) -
Three‐Component Aminoarylation of Electron‐Rich Alkenes by Merging Photoredox with Nickel Catalysis
por: Jiang, Heng, et al.
Publicado: (2021) -
A Chiral Pentafluorinated Isopropyl Group via Iodine(I)/(III) Catalysis
por: Meyer, Stephanie, et al.
Publicado: (2021)