A Selective and General Cobalt‐Catalyzed Hydroaminomethylation of Olefins to Amines

A new cobalt catalyst is presented for the domino hydroformylation‐reductive amination reaction of olefins. The optimal Co‐tert‐BuPy‐Xantphos catalyst shows good to excellent linear‐to‐branched (n/iso) regioselectivity for the reactions of aliphatic alkenes with aromatic amines under mild conditions...

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Detalles Bibliográficos
Autores principales: Yang, Ji, Delolo, Fábio G., Spannenberg, Anke, Jackstell, Ralf, Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299624/
https://www.ncbi.nlm.nih.gov/pubmed/34738697
http://dx.doi.org/10.1002/anie.202112597

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299624/
https://www.ncbi.nlm.nih.gov/pubmed/34738697
http://dx.doi.org/10.1002/anie.202112597

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