Electrophilic Fluorination of Alkenes via Bora‐Wagner–Meerwein Rearrangement. Access to β‐Difluoroalkyl Boronates

The electrophilic fluorination of geminal alkyl substituted vinyl‐Bmida derivatives proceeds via bora‐Wagner–Meerwein rearrangement. According to DFT modelling studies this rearrangement occurs with a low activation barrier via a bora‐cyclopropane shaped TS. The Bmida group has a larger migration ap...

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Detalles Bibliográficos
Autores principales: Wang, Qiang, Biosca, Maria, Himo, Fahmi, Szabó, Kálmán J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299629/
https://www.ncbi.nlm.nih.gov/pubmed/34613633
http://dx.doi.org/10.1002/anie.202109461

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299629/
https://www.ncbi.nlm.nih.gov/pubmed/34613633
http://dx.doi.org/10.1002/anie.202109461

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