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High‐Throughput Discovery of a Rhombohedral Twelve‐Connected Zirconium‐Based Metal‐Organic Framework with Ordered Terephthalate and Fumarate Linkers
We report a metal‐organic framework where an ordered array of two linkers with differing length and geometry connect [Zr(6)(OH)(4)O(4)](12+) clusters into a twelve‐connected fcu net that is rhombohedrally distorted from cubic symmetry. The ordered binding of equal numbers of terephthalate and fumara...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299659/ https://www.ncbi.nlm.nih.gov/pubmed/34519411 http://dx.doi.org/10.1002/anie.202108150 |