How 5 f Electron Polarisability Drives Covalency and Selectivity in Actinide N‐Donor Complexes

We report a series of isostructural tetravalent actinide (Th, U−Pu) complexes with the N‐donor ligand N,N’‐ethylene‐bis((pyrrole‐2‐yl)methanimine) (H(2) L, H(2)pyren). Structural data from SC‐XRD analysis reveal [An(pyren)(2)] complexes with different An−N(imine) versus An−N(pyrrolide) bond lengths....

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Detalles Bibliográficos
Autores principales: Köhler, Luisa, Patzschke, Michael, Schmidt, Moritz, Stumpf, Thorsten, März, Juliane
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299701/
https://www.ncbi.nlm.nih.gov/pubmed/34747538
http://dx.doi.org/10.1002/chem.202102849

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299701/
https://www.ncbi.nlm.nih.gov/pubmed/34747538
http://dx.doi.org/10.1002/chem.202102849

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