Steric Repulsion Induced Conformational Switch in Supramolecular Structures

Inspired by the rigidified architecture of ‘picket‐fence’ systems, we propose a strategy utilizing strain to impose intramolecular tension in already peripherally overcrowded structures leading to selective atropisomeric conversion. Employing this approach, tuneable shape‐persistent porphyrin confor...

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Detalles Bibliográficos
Autores principales: Norvaiša, Karolis, Maguire, Sophie, Donohoe, Claire, O'Brien, John E., Twamley, Brendan, Gomes‐da‐Silva, Ligia C., Senge, Mathias O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299809/
https://www.ncbi.nlm.nih.gov/pubmed/34792217
http://dx.doi.org/10.1002/chem.202103879

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299809/
https://www.ncbi.nlm.nih.gov/pubmed/34792217
http://dx.doi.org/10.1002/chem.202103879

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