Synthesis and Reactivity of a Neutral Homocyclic Silylene

Isolation of the neutral homocyclic silylene 2 is possible via amine ligand abstraction with potassium graphite (KC(8)) and subsequent reaction with SiMe(3)Cl from a bicyclic silicon(I) amide J. This reaction proceeds via an anionic homoaromatic silicon ring compound 1 as an intermediate. The twofol...

Descripción completa

Detalles Bibliográficos
Autores principales: Keuter, Jan, Hepp, Alexander, Massolle, Anja, Neugebauer, Johannes, Mück‐Lichtenfeld, Christian, Lips, Felicitas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299817/
https://www.ncbi.nlm.nih.gov/pubmed/34797603
http://dx.doi.org/10.1002/anie.202114485

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299817/
https://www.ncbi.nlm.nih.gov/pubmed/34797603
http://dx.doi.org/10.1002/anie.202114485

Ejemplares similares