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Synthesis and Reactivity of a Neutral Homocyclic Silylene

Isolation of the neutral homocyclic silylene 2 is possible via amine ligand abstraction with potassium graphite (KC(8)) and subsequent reaction with SiMe(3)Cl from a bicyclic silicon(I) amide J. This reaction proceeds via an anionic homoaromatic silicon ring compound 1 as an intermediate. The twofol...

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Detalles Bibliográficos
Autores principales:	Keuter, Jan, Hepp, Alexander, Massolle, Anja, Neugebauer, Johannes, Mück‐Lichtenfeld, Christian, Lips, Felicitas
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299817/ https://www.ncbi.nlm.nih.gov/pubmed/34797603 http://dx.doi.org/10.1002/anie.202114485

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