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Base‐Mediated Radical Borylation of Alkyl Sulfones

A practical and direct method was developed for the production of versatile alkyl boronate esters via transition metal‐free borylation of primary and secondary alkyl sulfones. The key to the success of the strategy is the use of bis(neopentyl glycolato) diboron (B(2)neop(2)), with a stoichiometric a...

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Detalles Bibliográficos
Autores principales: Huang, Mingming, Hu, Jiefeng, Krummenacher, Ivo, Friedrich, Alexandra, Braunschweig, Holger, Westcott, Stephen A., Radius, Udo, Marder, Todd B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299846/
https://www.ncbi.nlm.nih.gov/pubmed/34713940
http://dx.doi.org/10.1002/chem.202103866