An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small‐Molecule Activation and Rearrangement Chemistry

A one‐pot synthesis of a CAAC‐stabilized, unsymmetrical, cyclic diborene was achieved via consecutive two‐electron reduction steps from an adduct of CAAC and B(2)Br(4)(SMe(2))(2). Theoretical studies revealed that this diborene has a considerably smaller HOMO–LUMO gap than those of reported NHC‐ and...

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Detalles Bibliográficos
Autores principales: Lu, Wei, Jayaraman, Arumugam, Fantuzzi, Felipe, Dewhurst, Rian D., Härterich, Marcel, Dietz, Maximilian, Hagspiel, Stephan, Krummenacher, Ivo, Hammond, Kai, Cui, Jingjing, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299934/
https://www.ncbi.nlm.nih.gov/pubmed/34750945
http://dx.doi.org/10.1002/anie.202113947

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299934/
https://www.ncbi.nlm.nih.gov/pubmed/34750945
http://dx.doi.org/10.1002/anie.202113947

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