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Tris(tetramethylguanidinyl)phosphine: The Simplest Non‐ionic Phosphorus Superbase and Strongly Donating Phosphine Ligand

We report the synthesis and properties of the much sought‐after tris(1,1,3,3‐tetramethylguanidinyl) phosphine P(tmg)(3), a crystalline, superbasic phosphine accessible through a short and scalable procedure from the cheap and commercially available bulk chemicals 1,1,3,3‐tetramethylguanidine, tris(d...

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Detalles Bibliográficos
Autores principales: Buß, Florenz, Röthel, Maike B., Werra, Janina A., Rotering, Philipp, Wilm, Lukas F. B., Daniliuc, Constantin G., Löwe, Pawel, Dielmann, Fabian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9300019/
https://www.ncbi.nlm.nih.gov/pubmed/34793627
http://dx.doi.org/10.1002/chem.202104021