A Genuine Stannylone with a Monoatomic Two‐Coordinate Tin(0) Atom Supported by a Bis(silylene) Ligand

The monoatomic zero‐valent tin complex (stannylone) {[Si(II)(Xant)Si(II)]Sn(0)} 5 stabilized by a bis(silylene)xanthene ligand, [Si(II)(Xant)Si(II)=PhC(NtBu)(2)Si(Xant)Si(NtBu)(2)CPh], and its bis‐tetracarbonyliron complex {[Si(II)(Xant)Si(II)]Sn(0)[Fe(CO)(4)](2)} 4 are reported. The stannylone 5 be...

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Detalles Bibliográficos
Autores principales: Xu, Jian, Dai, Chenshu, Yao, Shenglai, Zhu, Jun, Driess, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9300062/
https://www.ncbi.nlm.nih.gov/pubmed/34787947
http://dx.doi.org/10.1002/anie.202114073

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9300062/
https://www.ncbi.nlm.nih.gov/pubmed/34787947
http://dx.doi.org/10.1002/anie.202114073

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