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Solvothermal Synthesis of [Cr(7)S(8)(en)(8)Cl(2)]Cl(3) ⋅ 2H(2)O with Magnetically Frustrated [Cr(7)S(8)](5+) Double‐Cubes
A novel transition metal chalcohalide [Cr(7)S(8)(en)(8)Cl(2)]Cl(3) ⋅ 2H(2)O, with [Cr(7)S(8)](5+) dicubane cationic clusters, has been synthesized by a low temperature solvothermal method, using dimethyl sulfoxide (DMSO) and ethylenediamine (en) solvents. Ethylenediamine ligand exhibits bi‐ and mono...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9300142/ https://www.ncbi.nlm.nih.gov/pubmed/34757673 http://dx.doi.org/10.1002/chem.202103761 |