Non‐Heme‐Iron‐Mediated Selective Halogenation of Unactivated Carbon−Hydrogen Bonds

Oxidation of the iron(II) precursor [(L(1))Fe(II)Cl(2)], where L(1) is a tetradentate bispidine, with soluble iodosylbenzene ((s)PhIO) leads to the extremely reactive ferryl oxidant [(L(1))(Cl)Fe(IV)=O](+) with a cis disposition of the chlorido and oxido coligands, as observed in non‐heme halogenase...

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Detalles Bibliográficos
Autores principales: Bleher, Katharina, Comba, Peter, Faltermeier, Dieter, Gupta, Ashutosh, Kerscher, Marion, Krieg, Saskia, Martin, Bodo, Velmurugan, Gunasekaran, Yang, Shuyi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9300152/
https://www.ncbi.nlm.nih.gov/pubmed/34792224
http://dx.doi.org/10.1002/chem.202103452

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9300152/
https://www.ncbi.nlm.nih.gov/pubmed/34792224
http://dx.doi.org/10.1002/chem.202103452

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