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Non‐Heme‐Iron‐Mediated Selective Halogenation of Unactivated Carbon−Hydrogen Bonds
Oxidation of the iron(II) precursor [(L(1))Fe(II)Cl(2)], where L(1) is a tetradentate bispidine, with soluble iodosylbenzene ((s)PhIO) leads to the extremely reactive ferryl oxidant [(L(1))(Cl)Fe(IV)=O](+) with a cis disposition of the chlorido and oxido coligands, as observed in non‐heme halogenase...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9300152/ https://www.ncbi.nlm.nih.gov/pubmed/34792224 http://dx.doi.org/10.1002/chem.202103452 |