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Metal-free synthesis of C2-quaternary indolinones by (NH(4))(2)S(2)O(8) mediated oxidative dearomatization of indoles

An efficient metal-free, (NH(4))(2)S(2)O(8) mediated oxidative dearomatization of indoles for the construction of C2-quaternary indolinones was disclosed. A series of C2-quaternary indolinones derivatives with good functional group tolerance were obtained in moderate to excellent yields. This method...

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Detalles Bibliográficos
Autores principales: Dong, Yu, Qian, Jun-Hu, Chen, Xiang-Long, Jiang, Hui, Li, Xue, Zhou, Qiang, Mei, Ting, Shi, Zhi-Chuan, Li, Zhong-Hui, He, Bing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9301541/
https://www.ncbi.nlm.nih.gov/pubmed/35919833
http://dx.doi.org/10.1039/d2ra04191j